As of 07/12/05 there are 1056 structures in the database. A Best Lewis Structure and Donor Acceptor Interactions Tutorial is available to help you interpret those output sections. These Lewis structure calculations are done using NBO Analysis. Answer some Study Questions to help your understanding of some interesting chemistry. Apr 01, 2013 Lewis structures are a way to write chemical compounds where all the atoms and electrons are shown. Sometimes, people have a lot of trouble learning how to do this. However, using the methods on this page, you should have very little trouble. A step-by-step explanation of how to draw the BrF3 Lewis Structure For the BrF3 Lewis structure the total number of valence electrons (found on the periodic. Created Date: 1/9/2015 4:30:47 PM.
Learning Objective
1. Draw a Lewis electron dot diagram for an atom or a monatomic ion.
In almost all cases, chemical bonds are formed by interactions of valence electrons in atoms. To facilitate our understanding of how valence electrons interact, a simple way of representing those valence electrons would be useful.
A Lewis electron dot diagram (or electron dot diagram or a Lewis diagram or a Lewis structure) is a representation of the valence electrons of an atom that uses dots around the symbol of the element. The number of dots equals the number of valence electrons in the atom. These dots are arranged to the right and left and above and below the symbol, with no more than two dots on a side. (It does not matter what order the positions are used.) For example, the Lewis electron dot diagram for hydrogen is simply
Because the side is not important, the Lewis electron dot diagram could also be drawn as follows:
The electron dot diagram for helium, with two valence electrons, is as follows:
By putting the two electrons together on the same side, we emphasize the fact that these two electrons are both in the 1s subshell; this is the common convention we will adopt, although there will be exceptions later. The next atom, lithium, has an electron configuration of 1s22s1, so it has only one electron in its valence shell. Its electron dot diagram resembles that of hydrogen, except the symbol for lithium is used:
Beryllium has two valence electrons in its 2s shell, so its electron dot diagram is like that of helium:
The next atom is boron. Its valence electron shell is 2s22p1, so it has three valence electrons. The third electron will go on another side of the symbol:
Again, it does not matter on which sides of the symbol the electron dots are positioned.
For carbon, there are four valence electrons, two in the 2s subshell and two in the 2p subshell. As usual, we will draw two dots together on one side, to represent the 2s electrons. However, conventionally, we draw the dots for the two p electrons on different sides. As such, the electron dot diagram for carbon is as follows:
With nitrogen, which has three p electrons, we put a single dot on each of the three remaining sides:
For oxygen, which has four p electrons, we now have to start doubling up on the dots on one other side of the symbol. When doubling up electrons, make sure that a side has no more than two electrons.
Fluorine and neon have seven and eight dots, respectively:
With the next element, sodium, the process starts over with a single electron because sodium has a single electron in its highest-numbered shell, the n = 3 shell. By going through the periodic table, we see that the Lewis electron dot diagrams of atoms will never have more than eight dots around the atomic symbol.
Example 1
What is the Lewis electron dot diagram for each element?
- aluminum
- selenium
Solution
The valence electron configuration for aluminum is 3s23p1. So it would have three dots around the symbol for aluminum, two of them paired to represent the 3s electrons:
The valence electron configuration for selenium is 4s24p4. In the highest-numbered shell, the n = 4 shell, there are six electrons. Its electron dot diagram is as follows:
Test Yourself
What is the Lewis electron dot diagram for each element?
- phosphorus
- argon
Answer
For atoms with partially filled d or f subshells, these electrons are typically omitted from Lewis electron dot diagrams. For example, the electron dot diagram for iron (valence shell configuration 4s23d6) is as follows:
Elements in the same column of the periodic table have similar Lewis electron dot diagrams because they have the same valence shell electron configuration. Thus the electron dot diagrams for the first column of elements are as follows:
Monatomic ions are atoms that have either lost (for cations) or gained (for anions) electrons. Electron dot diagrams for ions are the same as for atoms, except that some electrons have been removed for cations, while some electrons have been added for anions. Thus in comparing the electron configurations and electron dot diagrams for the Na atom and the Na+ ion, we note that the Na atom has a single valence electron in its Lewis diagram, while the Na+ ion has lost that one valence electron:
![Lewis Dot Structure Calculator Wolfram Lewis Dot Structure Calculator Wolfram](https://mhreviews.files.wordpress.com/2011/07/wolfram-chemistry-1-start-screen.png?w=584)
Technically, the valence shell of the Na+ ion is now the n = 2 shell, which has eight electrons in it. So why do we not put eight dots around Na+? Conventionally, when we show electron dot diagrams for ions, we show the original valence shell of the atom, which in this case is the n = 3 shell and empty in the Na+ ion.
In making cations, electrons are first lost from the highest numbered shell, not necessarily the last subshell filled. For example, in going from the neutral Fe atom to the Fe2+ ion, the Fe atom loses its two 4s electrons first, not its 3d electrons, despite the fact that the 3d subshell is the last subshell being filled. Thus we have
Anions have extra electrons when compared to the original atom. Here is a comparison of the Cl atom with the Cl− ion:
Example 2
What is the Lewis electron dot diagram for each ion?
- Ca2+
- O2−
Solution
Having lost its two original valence electrons, the Lewis electron dot diagram is just Ca2+.
Ca2+
The O2− ion has gained two electrons in its valence shell, so its Lewis electron dot diagram is as follows:
Test Yourself
The valence electron configuration of thallium, whose symbol is Tl, is 6s25d106p1. What is the Lewis electron dot diagram for the Tl+ ion?
Answer
Key Takeaways
- Lewis electron dot diagrams use dots to represent valence electrons around an atomic symbol.
- Lewis electron dot diagrams for ions have fewer (for cations) or more (for anions) dots than the corresponding atom.
Exercises
Explain why the first two dots in a Lewis electron dot diagram are drawn on the same side of the atomic symbol.
Is it necessary for the first dot around an atomic symbol to go on a particular side of the atomic symbol?
What column of the periodic table has Lewis electron dot diagrams with two electrons?
What column of the periodic table has Lewis electron dot diagrams that have six electrons in them?
Draw the Lewis electron dot diagram for each element.
a) strontium
b) silicon
6. Draw the Lewis electron dot diagram for each element.
a) krypton
b) sulfur
7. Draw the Lewis electron dot diagram for each element.
a) titanium
b) phosphorus
8. Draw the Lewis electron dot diagram for each element.
a) bromine
b) gallium
9. Draw the Lewis electron dot diagram for each ion.
a) Mg2+
b) S2−
10. Draw the Lewis electron dot diagram for each ion.
a) In+
b) Br−
11. Draw the Lewis electron dot diagram for each ion.
a) Fe2+
b) N3−
12. Draw the Lewis electron dot diagram for each ion.
a) H+
b) H−
Answers
1.
The first two electrons in a valence shell are s electrons, which are paired.
3.
the second column of the periodic table
5.
a)
b)
7.
a)
b)
Lewis Dot Structure Calculator Wolfram Model
9.
a) Mg2+
b)
11.
Lewis Dot Structure Calculator Wolfram Chart
a) Fe2+
b)
Bonding is pretty fundamental, as it determines the shape of a molecule, which in turn determines how a molecule behaves. Wolfram|Alpha now supports Lewis structures—diagrams that show both the bonded and unbonded electrons in a molecule. But as any good teacher will tell you, even more important than finding the answer is the procedure used to get that answer. Thus, Wolfram|Alpha is expanding its Step-by-step interface into the realm of chemical bonding (with even more Step-by-step functionality coming soon).
Molecules are composed of atoms, bonds, and unbonded electrons. The atoms (represented by letters) are connected by bonds (pairs of electrons represented by lines), with any 'leftover' or unbonded electrons on each atom displayed as dots. For example, here are the Lewis structures of water and ethylene.
With one click of a button, Wolfram|Alpha Pro users can access Step-by-step functionality that will guide them through the process of drawing a Lewis structure.
Wolfram|Alpha now helps users understand the principles behind bonding and chemical structures. With these steps, users can go above and beyond just seeing what the Lewis structure of nitrogen dioxide (NO2) looks like. The Step-by-step interface includes these features:
![Lewis dot structure builder Lewis dot structure builder](https://codeandfootball.files.wordpress.com/2012/01/wa_logit_solve.jpg)
As of 07/12/05 there are 1056 structures in the database. A Best Lewis Structure and Donor Acceptor Interactions Tutorial is available to help you interpret those output sections. These Lewis structure calculations are done using NBO Analysis. Answer some Study Questions to help your understanding of some interesting chemistry. Apr 01, 2013 Lewis structures are a way to write chemical compounds where all the atoms and electrons are shown. Sometimes, people have a lot of trouble learning how to do this. However, using the methods on this page, you should have very little trouble. A step-by-step explanation of how to draw the BrF3 Lewis Structure For the BrF3 Lewis structure the total number of valence electrons (found on the periodic. Created Date: 1/9/2015 4:30:47 PM.
Learning Objective
1. Draw a Lewis electron dot diagram for an atom or a monatomic ion.
In almost all cases, chemical bonds are formed by interactions of valence electrons in atoms. To facilitate our understanding of how valence electrons interact, a simple way of representing those valence electrons would be useful.
A Lewis electron dot diagram (or electron dot diagram or a Lewis diagram or a Lewis structure) is a representation of the valence electrons of an atom that uses dots around the symbol of the element. The number of dots equals the number of valence electrons in the atom. These dots are arranged to the right and left and above and below the symbol, with no more than two dots on a side. (It does not matter what order the positions are used.) For example, the Lewis electron dot diagram for hydrogen is simply
Because the side is not important, the Lewis electron dot diagram could also be drawn as follows:
The electron dot diagram for helium, with two valence electrons, is as follows:
By putting the two electrons together on the same side, we emphasize the fact that these two electrons are both in the 1s subshell; this is the common convention we will adopt, although there will be exceptions later. The next atom, lithium, has an electron configuration of 1s22s1, so it has only one electron in its valence shell. Its electron dot diagram resembles that of hydrogen, except the symbol for lithium is used:
Beryllium has two valence electrons in its 2s shell, so its electron dot diagram is like that of helium:
The next atom is boron. Its valence electron shell is 2s22p1, so it has three valence electrons. The third electron will go on another side of the symbol:
Again, it does not matter on which sides of the symbol the electron dots are positioned.
For carbon, there are four valence electrons, two in the 2s subshell and two in the 2p subshell. As usual, we will draw two dots together on one side, to represent the 2s electrons. However, conventionally, we draw the dots for the two p electrons on different sides. As such, the electron dot diagram for carbon is as follows:
With nitrogen, which has three p electrons, we put a single dot on each of the three remaining sides:
For oxygen, which has four p electrons, we now have to start doubling up on the dots on one other side of the symbol. When doubling up electrons, make sure that a side has no more than two electrons.
Fluorine and neon have seven and eight dots, respectively:
With the next element, sodium, the process starts over with a single electron because sodium has a single electron in its highest-numbered shell, the n = 3 shell. By going through the periodic table, we see that the Lewis electron dot diagrams of atoms will never have more than eight dots around the atomic symbol.
Example 1
What is the Lewis electron dot diagram for each element?
- aluminum
- selenium
Solution
The valence electron configuration for aluminum is 3s23p1. So it would have three dots around the symbol for aluminum, two of them paired to represent the 3s electrons:
The valence electron configuration for selenium is 4s24p4. In the highest-numbered shell, the n = 4 shell, there are six electrons. Its electron dot diagram is as follows:
Test Yourself
What is the Lewis electron dot diagram for each element?
- phosphorus
- argon
Answer
For atoms with partially filled d or f subshells, these electrons are typically omitted from Lewis electron dot diagrams. For example, the electron dot diagram for iron (valence shell configuration 4s23d6) is as follows:
Elements in the same column of the periodic table have similar Lewis electron dot diagrams because they have the same valence shell electron configuration. Thus the electron dot diagrams for the first column of elements are as follows:
Monatomic ions are atoms that have either lost (for cations) or gained (for anions) electrons. Electron dot diagrams for ions are the same as for atoms, except that some electrons have been removed for cations, while some electrons have been added for anions. Thus in comparing the electron configurations and electron dot diagrams for the Na atom and the Na+ ion, we note that the Na atom has a single valence electron in its Lewis diagram, while the Na+ ion has lost that one valence electron:
Technically, the valence shell of the Na+ ion is now the n = 2 shell, which has eight electrons in it. So why do we not put eight dots around Na+? Conventionally, when we show electron dot diagrams for ions, we show the original valence shell of the atom, which in this case is the n = 3 shell and empty in the Na+ ion.
In making cations, electrons are first lost from the highest numbered shell, not necessarily the last subshell filled. For example, in going from the neutral Fe atom to the Fe2+ ion, the Fe atom loses its two 4s electrons first, not its 3d electrons, despite the fact that the 3d subshell is the last subshell being filled. Thus we have
Anions have extra electrons when compared to the original atom. Here is a comparison of the Cl atom with the Cl− ion:
Example 2
What is the Lewis electron dot diagram for each ion?
- Ca2+
- O2−
Solution
Having lost its two original valence electrons, the Lewis electron dot diagram is just Ca2+.
Ca2+
The O2− ion has gained two electrons in its valence shell, so its Lewis electron dot diagram is as follows:
Test Yourself
The valence electron configuration of thallium, whose symbol is Tl, is 6s25d106p1. What is the Lewis electron dot diagram for the Tl+ ion?
Answer
Key Takeaways
- Lewis electron dot diagrams use dots to represent valence electrons around an atomic symbol.
- Lewis electron dot diagrams for ions have fewer (for cations) or more (for anions) dots than the corresponding atom.
Exercises
Explain why the first two dots in a Lewis electron dot diagram are drawn on the same side of the atomic symbol.
Is it necessary for the first dot around an atomic symbol to go on a particular side of the atomic symbol?
What column of the periodic table has Lewis electron dot diagrams with two electrons?
What column of the periodic table has Lewis electron dot diagrams that have six electrons in them?
Draw the Lewis electron dot diagram for each element.
a) strontium
b) silicon
6. Draw the Lewis electron dot diagram for each element.
a) krypton
b) sulfur
7. Draw the Lewis electron dot diagram for each element.
a) titanium
b) phosphorus
8. Draw the Lewis electron dot diagram for each element.
a) bromine
b) gallium
9. Draw the Lewis electron dot diagram for each ion.
a) Mg2+
b) S2−
10. Draw the Lewis electron dot diagram for each ion.
a) In+
b) Br−
11. Draw the Lewis electron dot diagram for each ion.
a) Fe2+
b) N3−
12. Draw the Lewis electron dot diagram for each ion.
a) H+
b) H−
Answers
1.
The first two electrons in a valence shell are s electrons, which are paired.
3.
the second column of the periodic table
5.
a)
b)
7.
a)
b)
Lewis Dot Structure Calculator Wolfram Model
9.
a) Mg2+
b)
11.
Lewis Dot Structure Calculator Wolfram Chart
a) Fe2+
b)
Bonding is pretty fundamental, as it determines the shape of a molecule, which in turn determines how a molecule behaves. Wolfram|Alpha now supports Lewis structures—diagrams that show both the bonded and unbonded electrons in a molecule. But as any good teacher will tell you, even more important than finding the answer is the procedure used to get that answer. Thus, Wolfram|Alpha is expanding its Step-by-step interface into the realm of chemical bonding (with even more Step-by-step functionality coming soon).
Molecules are composed of atoms, bonds, and unbonded electrons. The atoms (represented by letters) are connected by bonds (pairs of electrons represented by lines), with any 'leftover' or unbonded electrons on each atom displayed as dots. For example, here are the Lewis structures of water and ethylene.
With one click of a button, Wolfram|Alpha Pro users can access Step-by-step functionality that will guide them through the process of drawing a Lewis structure.
Wolfram|Alpha now helps users understand the principles behind bonding and chemical structures. With these steps, users can go above and beyond just seeing what the Lewis structure of nitrogen dioxide (NO2) looks like. The Step-by-step interface includes these features:
- It is completely self-contained: All relevant information (valence electron count, electronegativities of atoms, etc.) is inside of the steps if needed.
- Explains why bonds occur and distinguishes between bonding types: The interface determines which bonds should be single, double, or triple and why. This is truly at the heart of chemical bonding. (We give an in-depth explanation of different bonding types below.)
- Points out exceptions: Wolfram|Alpha teaches you how to correctly deal with these 'special cases,' so you don't fear them.
- States interesting properties: Wolfram|Alpha draws your attention when neat things are happening inside of a molecule (special bond types, expanded valence shells, etc). In particular, Wolfram|Alpha will point out when there are multiple ways to draw a molecule rather than keeping you guessing on whether another answer is 'as correct' as the given one.
Let's go through some examples to get a sense of what drawing a Lewis structure entails. In order to do this, we need three basic chemistry facts.
The first fact is a definition: the columns of the periodic table are labeled from 1 to 18, and elements in columns 1, 2, 3, …, 18 are said to be in group 1, 2, 3, …, 18. The group numbers are shown above the columns in the following periodic table.
The second fact is that elements in groups 1, 2, 13, 14, 15, 16, 17, and 18 have 1, 2, 3, 4, 5, 6, 7, and 8 valence electrons, which is the number of electrons they have in their outermost shell (compared to these outermost electrons, the innermost electrons barely have an effect and hence can be ignored). I have skipped over groups 3 through 12 on purpose—more on that below.
The third and final fact we need is that every atom (except hydrogen or helium) wants to have 8 valence electrons. The most common way for atoms to gain additional valence electrons is by sharing electrons and forming covalent bonds. A covalent bond occurs when two atoms each place one of their electrons into the space between them, thereby allowing both atoms to act as if both electrons are a part of their valence shell. By donating one electron into the bond and getting to feel both electrons from the bond, each of the atoms increases its valence electron count by 1 electron. Returning to the Lewis diagram for water:
Oxygen (in group 16) began with 6 valence electrons while both of the hydrogen atoms (group 1) began with 1 valence electron. The oxygen donated 1 electron to bond together with each hydrogen's electron (note that the two bonds have the colors of both atoms, since each atom donated 1 electron to make up the bond). Thus oxygen now has 8 valence electrons: 4 from its unbonded electron and 4 more from its two covalent bonds (since each bond gives 2 electrons). Both hydrogen atoms feel like they have 2 valence electrons from their bond with oxygen.
The observant reader will note that I have completely skipped over ionic bonding. By convention, Lewis structures only apply to covalently bonded molecules, and we will follow that philosophy here. Other types of bonds (such as hydrogen bonds) are too weak to influence the location of the electrons relative to their atoms, so we are safe in only considering covalent bonds. Additionally, I have completely neglected the transition metals (atoms with group numbers ranging from 3 to 12). Truthfully, the transition metals do not behave with such simple rules as the other elements, so for the purposes of this discussion, we will pretend they do not exist (just close your eyes and pretend!).
Lewis Structure Calculator
Now that we have gotten past the basics, let's get to some points that you might not hear in any introductory chemistry class. What happens to hydrogen? Is it happy with only one bond? Actually, it is. Hence, oftentimes people have the misconception that all elements in groups 1 and 2 only 'want' 2 valence electrons (in chemistry classes, the party line is that having a fully filled s valence shell is more stable than having a partially filled p shell).
Yet that is incorrect: every element in groups 1 and 2 (except hydrogen) wants 8 electrons. Because group 1 elements only have 1 electron, they can only participate in one covalent bond. But any group 2 element (with 2 valence electrons available for bonding) will always have two bonds, and any group 13 element (with 3 valence electrons) will always have at least three bonds (in fact, group 13 elements sometimes manage to snag an extra electron and make four bonds). So the general rule is that all atoms want 8 valence electrons, and even atoms that cannot achieve 8 valence electrons try to get as close as possible. As for the molecules that can covalently bond to get 8 valence electrons, we can (correctly) predict that in general, group 14, 15, 16, and 17 atoms will have four, three, two, and one covalent bonds, respectively. Finally, we expect that group 18 atoms, which start out with 8 valence electrons, will not want to form covalent bonds, and hence will rarely show up in any molecule. It is this property of low reactivity that has led to group 18 elements being referred to as the inert gases or noble gases. (Helium, being a special case, is also considered a noble gas, even though it only has 2 valence electrons.) The following grid shows an example of the typical bonding seen from each group:
To recap, molecules will covalently bond in order to bump their valence electron count as close to 8 valence electrons as possible. Now that we have this theory under our belt, let's apply it and figure out the Lewis structure of an important molecule that plays a vital role in many peoples' lives: caffeine. We begin with the basic layout of caffeine, merely showing which atoms are bonded together but suppressing any double or triple bonds, as well as any unbonded electrons.
Using the group numbers found from the periodic table, hydrogen (group 1), carbon (group 14), nitrogen (group 15), and oxygen (group 16) have 1, 4, 5, and 6 valence electrons, respectively. Remembering that each covalent bond uses up 1 electron from each of the two bonded atoms, we can fill in the remaining electrons on each atom and highlight any atoms that do not have 8 valence electrons (hydrogen is not highlighted because it is the exceptional atom that wants only 2 valence electrons).
We are now faced with a simple puzzle where we want to connect adjacent highlighted atoms with additional bonds until they have 8 valence electrons. There is only one solution:
Having done this warm-up, let's consider the much larger and significantly more important (not to mention decidedly less unhealthy) molecule ATP. This time, we combine the first two steps together, showing the ATP molecule with single bonds and immediately highlighting all the atoms that want more valence electrons.
The eight highlighted carbon and nitrogen atoms on the bottom-left are very interesting in their own right (in fact, they form aromatic bonds, which are exceedingly interesting!), but we already know how to add bonds to complete their valence shells (hint: it takes four additional bonds). Instead, we will focus on the top-right of ATP where the highlighted oxygen atoms pose a problem. Each of the three highlighted oxygen atoms wants an additional bond in order to have 8 valence electrons, and each oxygen is bonded to a phosphorus atom with an additional electron available to form a bond. But these phosphorus atoms already have 8 valence electrons (in fact, they have 9). So what happens?
At this point, the situation turns into a fight scene. Oxygen wants to form a bond with phosphorus and attain 8 valence electrons while phosphorus wants to stay as close to 8 valence electrons as possible. (You might be wondering why phosphorus cannot happily accept the extra electrons. The answer lies in the fact that the extra electrons phosphorus acquires spill over into its d shell—sticking to my mantra of not discussing transition metals or their like, suffice it to say that phosphorus would prefer 8 valence electrons to 9, and 9 valence electrons to 10). The resolution of this struggle comes from comparing a property called electronegativity, which measures how strongly an atom wants an extra electron (in other words, how strongly an atom is willing to push to gets its way). The atom with the larger electronegativity will win: if oxygen has a larger electronegativity, then it will form a double bond with phosphorus; if phosphorus has the larger electronegativity, then it will remain single bonded to oxygen. As Wolfram|Alpha politely informs us:
Oxygen has the larger electronegativity, and hence we find the complete Lewis structure of ATP.
So, in the end, bonding occurs between two atoms in the following two cases:
1. When two adjacent molecules have an incomplete valence (and hence are both highlighted), they can form an additional bond to bring both atoms closer to 8 valence electrons.
2. A highlighted atom with large electronegativity (oxygen, in the case of ATP) can force an unhighlighted atom with smaller electronegativity (phosphorus in ATP) to expand its valence shell (for technical reasons having to do with the d shell, this can only happen if the unhighlighted atom is on the third row of the periodic table or lower).
So that's it: bonding in a nutshell. I think we should all give ourselves a big pat on the back and really enjoy this moment.
But don't get me wrong: this is not the whole story. Among the millions of discovered molecules there are exceptions to practically every rule, ranging from quirky oddities (such as an atom donating both electrons in order to make what is called a dipolar bond) to ridiculous outliers (such as making four covalent bonds, which typically takes 8 electrons, using only 3 electrons). Wolfram|Alpha will gallantly steer through all the stunts even the trickiest molecules can pull and show the correct Lewis structure.
But even some basic molecules can get very tricky. There are a variety of different procedures for generating Lewis structures. One of the most common procedures, which can be found in any standard textbook (such as Principles of Modern Chemistry) or simply by searching 'How to draw Lewis structures,' states that after determining which bonds should be made into double or triple bonds, you divvy up the remaining electrons from the most electronegative atom to the least electronegative atom. Unfortunately, this procedure will fail for as small and simple a molecule as nitrogen dioxide NO2; it predicts that of the 11 remaining electrons, 10 should go first and foremost to the more electronegative oxygen atom, leaving the nitrogen atom with a single electron. By contrast, our correct procedure above accounts for the fact that nitrogen started out with 5 electrons, so that after making three bonds it should have 2 unbonded electrons remaining. Similarly, oxygen started with 6 electrons and hence after making either one or two bonds, it should end up with 5 or 4 unbonded electrons, respectively.
Because this common procedure is so pervasive in textbooks and on the internet (as the name suggests), about half of the Lewis structures you get when searching for 'NO2 Lewis structure' are wrong. So next time someone shows you the incorrect Lewis structure of NO2, feel free to pull out Wolfram|Alpha and have it lay out the smackdown.
Having come to what appears to be the end of an epic quest to understand Lewis structures, let's do a quick reality check. The two cases of bonding discussed above are a great starting point, but to be robust enough to handle all the different cases out there, they need to be significantly expanded. For example, consider the class of ions (molecules with extra electrons either added to them or removed from them, giving them a net charge). If we focus on ions with a negative net charge such as phosphate, sulfate, or nitrate, you might suspect that the most electronegative atom (oxygen, in all three cases) will get an additional electron from the net charge. This makes sense, since oxygen naturally has the largest pull on the extra electron. But what happens when all the atoms have the same electronegativity? And what happens when this rule completely breaks down and a less electronegative atom gets the extra electron? The deeper you delve into such cases, the more mysteries seem to pop up. Such trains of thought can spiral out to infinity… and beyond! But that is a good thing: each iteration allows you to better characterize an important class of molecules that can only be competently handled once its scope is completely defined.
Lewis Dot Structure Generator
At the conclusion of this escapade into bonding, I find it important to step back and discuss the limitations of these results. The most important question to ask is: Do the rules discussed above really mirror the underlying principles governing molecular bonding? If they do, then you would expect to find simple arguments (like F = m a in physics) from which these rules naturally arise. (For example, in ATP, can you calculate the difference in energy between the actual molecule and the analogous version with single bonds between the highlighted oxygen and phosphorus atoms? Could such a calculation be made knowing only the difference in electronegativities of oxygen and phosphorus?) The truth is that no one knows. Chemists are divided about whether you can accurately model what is going on at the atomic level by only considering valence electrons; some chemists believe that you need another theory, such as molecular orbital theory, to truly understand the behavior of electrons. The waters are especially murky here because some chemical principles are derived by trying to explain the trends that we see in the data points currently available. Thus, such statements cannot truly be proved, but they can be disproved with counterexamples. So although the theory above holds up for the substantial chemical database we have at Wolfram|Alpha, I can't say that some other (potentially crazy and ridiculously complex) molecule out there will come about that will totally shatter this framework.
Lewis Dot Structure Calculator Wolfram Integral
But when that happens, it is simply time to roll out the ubiquitous exceptions list…